Using ffmpeg and avconv [Dec. 16, 2012, 12:12 p.m.]
A hands on look at command line encoding. Robert has been writing some help on this. I think he'll update this soon.
WebM
An overview of usefull ffmpeg/avconv options related to encoding WebM files.
http://wiki.webmproject.org/ffmpeg and http://ffmpeg.org/ffmpeg.html#libvpx
http://rodrigopolo.com/ffmpeg/cheats.html
Creating h264 files that work on many mobile devices
http://h264.code-shop.com/trac/wiki/Encoding
General x264 encoding guide
http://ffmpeg.org/trac/ffmpeg/wiki/x264EncodingGuide
Assessment Task
Create a video file with ffmpeg or aviconv